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Unsure which ceramic material to choose? You should ensure the ceramic you pick has enough fracture toughness to resist cracking and pressure. Zirkonia exhibits ultra-high toughness, making it your go-to choice.
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This guide will show you why Zirkonia is an outstanding choice and how it compares to other advanced ceramics.
What Do You Understand By Zirconia Fracture Toughness?
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Fracture toughness is a mechanical property that describes how able a material is, to control a crack from getting worse. For example, if you subject Zirconia to mechanical stress, its high fracture toughness can withstand the pressure.
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To calculate a material’s fracture toughness, apply the formula ‘KIC=Yσ√a’. The stress intensity factor (KIC) represents the Fracture toughness. Y stands for Geometry factor, σ stands for applied stress (MPa), and ‘a’ stands for rack length in meters. The higher the stress intensity value, the stronger the material.
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Zirconia is so mechanically strong because it undergoes transformation toughening. This occurs when you apply stress around a crack, inducing a phase transformation. The transformation changes Zirconia’s particles from a tetragonal to a monoclinic phase. Hence, the material absorbs energy, volume increases, and can prevent cracks from escalating.
Unique Properties Of Zirconia
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Phase transformation: Among all advanced ceramics, Zirconia is the only one that undergoes phase transformation. Think of this process as ‘self-healing’, where zirconia cells become strong enough to resist a fracture.
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Exemplary strength and high toughness: Superior toughness, Zirkonia’s best property, is not affected by conditions like room temperature.
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Zirconia is very hard, therefore it does not wear or tear easily.
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High thermal stability and low thermal conductivity: Therefore, Zirconia is a good thermal conductor that can withstand high temperatures.
PROPERTY |
ESTIMATED QUANTITY |
UNIT |
Fracture toughness |
6–17 |
MPa·m¹/² |
Flexural Strength |
630–1400 |
MPa |
Compressive Strength |
2000–5690 |
MPa |
Hardness |
12–14.5 |
GPa |
Thermal expansion |
9.0–10.0 |
x10⁻⁶/K |
Maximum use temp. |
1000–1500 |
°C |
Density |
5.7–6.07 |
g/cm³ |
How Zirconia Compares To Other Advanced Ceramics
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Alumina, Silicon Nitride, and Silicon Carbide among other advanced ceramics will offer you hardness and resistance to wear. In addition to that, Zirkonia gives you superior fracture toughness. The figure below shows you a comprehensive comparison of top ceramics.
Ceramic Material |
Fracture Toughness (MPa·m¹/²) |
Key properties of each |
Zirconia (ZrO₂) |
8–12 |
High toughness and phase transformation toughening |
Alumina (Al₂O₃) |
~4 |
Strong but exhibits a lower fracture toughness |
Silicon Carbide (SiC) |
~3–5 |
Very hard but can be brittle |
Silicon Nitride (Si₃N₄) |
~6–8 |
Balances toughness and strength well, therefore it’s used in high-performance applications |
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If you are interested in a material that can resist cracks or mechanical failures, choose Zirconia. If it’s not among your options, go for Silicon Nitride as it offers a good balance of toughness and strength.
Applications Of Zirconia Ceramics In Industries
Medical Industry
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Zirconia is very strong and durable, which makes it a perfect choice for dental implants and prosthetics. The material resembles your original teeth and is long-lasting. Additionally, Zirconia is biocompatible, ensuring that your teeth won’t resist the material.
Industrial Cutting Tools
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If you use sharp machining tools, Zirconia is your ideal ceramic. It provides them durability and the ability to remain sharp for a long time. Additionally, Zirconia enhances precision, facilitating high-quality work in your industry.
Aerospace Industry
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Zirconia ceramics are used in the aeroscope industry to facilitate thermal barrier coatings for jet engines. Zirconia’s good thermal conductivity prevents your aircraft’s engines from cracking even under extreme temperatures. This property further ensures your aircraft is fuel-efficient and contributes to high performance.
Electronics Industry
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Zirconia is applied in the electronics industry as an ideal component in solid oxide fuel cells. Zirconia is also used in insulators and substrates because of its insulation and thermal resistance properties. Zirconia can also store electrical energy, therefore ideal for ceramic capacitors, sensors, and high-power devices.
Laboratory Crucibles
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Zirconia is generally inert chemically, with high-temperature stability, which makes it ideal for manufacturing laboratory crucibles.
Jeweralies And Watch Components
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Zirconia’s hardness and scratch resistance make it ideal in the manufacture of watch components.
Factors You Should Consider When Choosing Zirconia Ceramics
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If you want to buy zirconia ceramics, you should understand their differences. Keep in mind the following tips to help you choose the right Zirconia ceramic.
What Grade Is It?
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Some of the zirconia ceramics pride superior fracture toughness but you find others do well in preventing wear. Therefore, be sure to choose the zirconia ceramic that best matches your requirements.
How Pure Is It?
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Purity is a key factor when it comes to zirconia ceramics. If the purity level is high, then your material will be more durable and even stronger. A good purity level will range from 95% pure. On the contrary, if the material has low purity, it means that it might be composed of impurities which weaken the material
Was Its Toughness Affected During Manufacturing?
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Various manufacturing processes affect Zirconia’s toughness—through controlling microstructure. Microstructure is influenced by factors like sintering temperature, pressure, and phase composition. All these factors affect the level of transformational toughening and durability. For you to get the best out of Zirconia, ensure that you choose a material whose toughness doesn’t change over time.
How to Choose the Right Ceramics Supplier
Where To Buy Ceramic Materials
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You can purchase ceramics from online suppliers and marketplaces, through online platforms. You can also purchase customized materials directly from the manufacturer. Some local suppliers sell ceramic materials, making purchases more convenient for you.
Factors To Consider Before Deciding Where To Buy
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Certification:
Check if the supplier is certified, to be sure that they value safety and performance. This will further assure you that they adhere to the highest quality standards.
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Expertise: Choose a supplier who understands zirconia ceramics in detail to ensure your needs are met.
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Innovation and Customization: Choose a supplier who is committed to ceramic innovation. This means that they can continuously refine their materials to improve performance. Additionally, customization will help in tailoring materials to meet your specific requirements and needs.
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Product Diversity: A good supplier should give you a range of advanced ceramics to meet your needs. From Zirconia to alumina and nitride.
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Your budget: Compare the pricing of various suppliers before you make a decision. However, note that cheap is not always the best. Ensure that your supplier offers a good balance in price and quality.
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Industry reputation and reliability: Read reviews from past clients so you can gauge the supplier’s reliability. Also, check how experienced the supplier is because experience and expertise are closely related.
Final Tips And Thoughts
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If your priority is toughness, consider Zirconia as your best shot.
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Be sure to choose Zirconia based on your intended application such as for medical use.
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Check for fracture toughness rating before you decide to buy a ceramic material.
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Finally, ensure that you are buying from a transparent, reliable, and experienced supplier.
Conclusion
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Advanced ceramics are recognized as strong, durable, and resistant to cracks. Zirconia stands out for exhibiting ultra-high toughness and a self-healing process. Consider factors like toughness retention before purchase, to ensure lasting performance!