Blog

Technical ceramics content with value for you!

Quartz vs. PBN in Plasma Reactors: Which Material Performs Better?

Published Date: 2025-04-28 15:02:25

In plasma reactors material selection is very important. Molten quartz is low price and UV transmittance, but PBN is known for its accuracy and heat resistance. In this guide I am going to compare quartz and Pyrolytic Boron Nitride (PBN), so that you can choose the best option for your reactor needs.


Plasma Reactor Challenges

Plasma reactors operate in harsh environments, creating unique challenges. There is reasons why the right material is important:

a) Thermal stability: The reactor generates high heat, so the material must withstand high temperatures without damage or deformation.

b) Chemical resistance: Reactive gases in plasma can corrode the surface. To avoid contamination, materials must withstand chemical reactions.

c) Electrical insulation: A strong electromagnetic field can interfere with the process of the reactor. Insulation material prevents confusion and ensures smooth operation.

By selecting materials that meet these needs, we protect systems, improve performance, and reduce downtime.

Features of Molten Quartz

Molten quartz has been a reliable material for many years, especially in high purity environments such as plasma reactors. why? Because it has reliable properties even under severe conditions:

1. High heat resistance

Quartz does not melt or break shape even at temperatures up to 1,600 ° C. Most high heat processes are sufficient. However, it is slightly sensitive to sudden temperature changes and can be broken by thermal shock. Think of it as a fragile glass cup that doesn’t want to pour boiling water right away.

2. Thermal shock resistance

Quartz is not fast in heat conduction and does not get hot or cool rapidly (ideal for stable processes), but is not ideal when rapid temperature changes occur frequently.

3. UV permeability

This is where quartz really shines! Quartz can transmit UV light (UV), making it ideal for industries that include UV-sensitive processes such as Plasma-Enhanced Chemical Vapor Deposition (PECVD).

4. Chemical Resistance

Quartz is resistant to most chemicals and maintains its structure even in reactive environments. However, when hydrofluoric acid, comes in, quartz has no means of defense and corrodes instantly, so be careful if it is part of the system.

Negative side

Quartz has many advantages, but processing is not easy. Because quartz is brittle, special diamond tools are required for accurate molding, increasing complexity and cost. In addition, cracks during processing are always a risk.


Understand PBN

PBN is a powerful material known for its ability to meet extreme heat, chemicals and complex processing needs. PBN is manufactured using the plasma chemical vapor phase growth method (plasma CVD method) to achieve first-class strength and durability. The reasons why PBN stands out are as follows:

1. Invincible thermal performance

Do you think quartz is strong in heat? PBN takes it to the next level. Instead of melting, sublimation (solid to gas) at a staggering 2,900°C. This means that PBN maintains reliability even under the highest and harshest conditions.

2. Electrical Insulation Master

PBN with more than 20kV/mm insulation resistance provides excellent electrical insulation. Ideal for reactors handling high voltage environments, preventing electrical interference.

3. Outstanding Chemical Resistance

Forget oxidation and instability under harsh plasma conditions. PBN maintains its integrity even when exposed to the most reactive chemicals and is always better than quartz in this field.

4. Easy machining

This is where PBN truly shines. Quartz is fragile and difficult to shape, but PBN is rugged, precise and easy to machine into complex shapes. Are there parts with complex details? PBN handles it easily.

5. Low porosity for special applications

Because PBN has a low porosity, catalysts can be incorporated, making it ideal for specific chemical processes. For this reason, it can be used in many applications in research and special industries.

Disadvantages

The only drawback? PBN has a high initial cost. However, if durability and long-term performance are of the utmost importance in setup, it is worth paying a penny.


Main Comparison of Molten Quartz and PBN

To explain the advantages of both, let’s compare molten quartz and PBN side by side:

Property

Molten quartz

PBN (Pyrolytic Boron Nitride)

Insulation resistance

10–15 kV/mm

Up to 20 kV/mm

Heat Resistance

Melts around 1,600°C; brittle under thermal cycling

Sublimates above 2,900°C; stable in extreme conditions

Plasma Stability

Resistant, but eroded under heavy bombing

Reactive ions and exceptional stability in vacuum environments

Machinability

difficult; High risk of breaking

Excellent; Precise and complex shapes are also possible.


Applications of PBN and Fused Quartz

Projects requiring materials to withstand high heat and pure settings benefit greatly from fused quartz. You may apply it as follows:

1. Light-Based Processes Like PECVD

Machines like plasma-enhanced chemical vapor deposition (PECVD) systems run well on fused quartz. Quartz does this perfectly; these systems have to let ultraviolet (UV) light pass through. It’s used to create thin film-coated materials or semiconductors.

2. For Containers That Are Heatproof

Fused quartz can be used to create reaction chambers, containers, or furnace tubes. These are crucial in locations where heat and chemicals are strong. It won’t easily break or corrode and remains robust even under protracted, hot conditions.

3. For Affordable, Simple Components

Fused quartz is a suitable option if you don’t require extremely exact designs. Without being too pricey, it can be used to create simple structures that endure well to heat and electricity or basic components like insulators.


When to Pick PBN

If your project calls for something stronger or more sophisticated, PBN is a sensible option. Here is how it might assist:

1. To Protect Heat in Plasma Reactors

Especially in plasma systems where temperatures rise and fall rapidly, PBN makes a good shield. It doesn’t break or melt under heat, so it’s excellent for protecting vital components.

2. For Special and Complex Shapes

PBN is simple to shape without breaking if you require a very particular form for a component, such a thin disc or components with tiny holes. This is excellent for creating complex components for precision-demanding machinery.

3. For Reactor Catalyst Work

If your reactor requires components with little apertures for chemicals to interact, PBN is ideal. Made into porous discs, it holds catalysts and aids in plasma deposition among other processes. These discs endure a long time and remain strong.

Using fused quartz for simpler, heat-resistant components and PBN for stronger, more sophisticated applications will help you to ensure your plasma reactors operate better and last longer. Select the one that best suits your project.


Things to Consider Before Selecting

1. Changes in Temperature

PBN is preferable if your system heats up and cools down significantly since it remains stable under severe temperature fluctuations.

2. Design and Shaping

PBN is the best option for complex shapes or exact components since it’s simple to machine without breaking.

3. Price

While PBN lasts longer and handles stress better, fused quartz is less expensive up front. PBN might help you save money later.

4. Resistance to Chemicals

PBN is more stable and won’t break down easily if your project calls for reactive settings or strong chemicals.

5. Requirements for Optical

Fused quartz is the appropriate choice if your work calls for UV transparency, such in plasma CVD or plasma deposition.


Why Choose PBN

PBN is ideal for plasma reactors.

  • PBN can handle very high temperatures without melting or collapsing shape. In other words, it does not break even under the highest temperature conditions.

  • It is easy to mold into fine and complex parts, so you can get exactly the design you need without worrying about cracks or breakage.

  • Due to its slight pores, it is suitable for retaining catalysts and is very useful during plasma processing.

  • PBN is difficult to rust, corrode and wear even when exposed to harsh chemicals and severe conditions.

  • The initial cost is expensive, but it can last longer, perform better, and save money by preventing future problems and replacements.

If you want a reliable, durable and long-lasting one, PBN is a smart choice.


Final Thoughts

If your project is sensitive to ultraviolet light, simple, or budget-limited, molten quartz is a great option. However, PBN is a better investment if durable items are needed under severe conditions.

Need a final decision? Contact us we will help you choose the best material for plasma reactor. Either molten quartz, PBN, or other advanced ceramic options, we will guide you.

 

Back